The large scale production of chemicals was an important development during the Industrial Revolution. The first of these was the production of sulphuric acid by the lead chamber process invented by the Englishman John Roebuck (James Watt's first partner) in 1746. He was able to greatly increase the scale of the manufacture by replacing the relatively expensive glass vessels formerly used with larger, less expensive chambers made of riveted sheets of lead. Instead of a few pounds at a time, he was able to make a hundred pounds (45 kg) or so at a time in each of the chambers.
The production of an alkali on a large scale became an important goal as well, and Nicolas Leblanc succeeded in 1791 in introducing a method for the production of sodium carbonate. The Leblanc process was a reaction of sulphuric acid with sodium chloride to give sodium sulphate and hydrochloric acid. The sodium sulphate was heated with limestone (calcium carbonate) and coal to give a mixture of sodium carbonate and calcium sulphide. Adding water separated the soluble sodium carbonate from the calcium sulphide. The process produced a large amount of pollution (the hydrochloric acid was initially vented to the air, and calcium sulphide was a useless waste product). Nonetheless, this synthetic soda ash proved economical compared to that from burning certain plants (barilla) or from kelp, which were the previously dominant sources of soda ash,[27] and also to potash (potassium carbonate) derived from hardwood ashes.
These two chemicals were very important because they enabled the introduction of a host of other inventions, replacing many small-scale operations with more cost-effective and controllable processes. Sodium carbonate had many uses in the glass, textile, soap, and paper industries. Early uses for sulphuric acid included pickling (removing rust) iron and steel, and for bleaching cloth.
The development of bleaching powder (calcium hypochlorite) by Scottish chemist Charles Tennant in about 1800, based on the discoveries of French chemist Claude Louis Berthollet, revolutionised the bleaching processes in the textile industry by dramatically reducing the time required (from months to days) for the traditional process then in use, which required repeated exposure to the sun in bleach fields after soaking the textiles with alkali or sour milk. Tennant's factory at St Rollox, North Glasgow, became the largest chemical plant in the world.
In 1824 Joseph Aspdin, a British brick layer turned builder, patented a chemical process for making portland cement which was an important advance in the building trades. This process involves sintering a mixture of clay and limestone to about 1400 °C, then grinding it into a fine powder which is then mixed with water, sand and gravel to produce concrete. Portland cement was used by the famous English engineer Marc Isambard Brunel several years later when constructing the Thames Tunnel.[28] Cement was used on a large scale in the construction of the London sewerage system a generation later.
The production of an alkali on a large scale became an important goal as well, and Nicolas Leblanc succeeded in 1791 in introducing a method for the production of sodium carbonate. The Leblanc process was a reaction of sulphuric acid with sodium chloride to give sodium sulphate and hydrochloric acid. The sodium sulphate was heated with limestone (calcium carbonate) and coal to give a mixture of sodium carbonate and calcium sulphide. Adding water separated the soluble sodium carbonate from the calcium sulphide. The process produced a large amount of pollution (the hydrochloric acid was initially vented to the air, and calcium sulphide was a useless waste product). Nonetheless, this synthetic soda ash proved economical compared to that from burning certain plants (barilla) or from kelp, which were the previously dominant sources of soda ash,[27] and also to potash (potassium carbonate) derived from hardwood ashes.
These two chemicals were very important because they enabled the introduction of a host of other inventions, replacing many small-scale operations with more cost-effective and controllable processes. Sodium carbonate had many uses in the glass, textile, soap, and paper industries. Early uses for sulphuric acid included pickling (removing rust) iron and steel, and for bleaching cloth.
The development of bleaching powder (calcium hypochlorite) by Scottish chemist Charles Tennant in about 1800, based on the discoveries of French chemist Claude Louis Berthollet, revolutionised the bleaching processes in the textile industry by dramatically reducing the time required (from months to days) for the traditional process then in use, which required repeated exposure to the sun in bleach fields after soaking the textiles with alkali or sour milk. Tennant's factory at St Rollox, North Glasgow, became the largest chemical plant in the world.
In 1824 Joseph Aspdin, a British brick layer turned builder, patented a chemical process for making portland cement which was an important advance in the building trades. This process involves sintering a mixture of clay and limestone to about 1400 °C, then grinding it into a fine powder which is then mixed with water, sand and gravel to produce concrete. Portland cement was used by the famous English engineer Marc Isambard Brunel several years later when constructing the Thames Tunnel.[28] Cement was used on a large scale in the construction of the London sewerage system a generation later.
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